Silver solid amalgam electrodes as sensors for chemical carcinogens

被引:93
作者
Barek, J [1 ]
Fischer, J
Navratil, T
Peckova, K
Yosypchuk, B
机构
[1] Charles Univ, Dept Analyt Chem, UNESCO Lab Environm Electrochem, Prague 12843 2, Czech Republic
[2] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, Prague 18223 8, Czech Republic
来源
SENSORS | 2006年 / 6卷 / 04期
关键词
solid amalgam electrodes; voltammetry; carcinogens; 3-nitrofluoranthene; Ostazine Orange;
D O I
10.3390/s6040445
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The applicability of differential pulse voltammetry (DPV) and adsorptive stripping voltammetry (AdSV) at a non-toxic meniscus-modified silver solid amalgam electrode (m-AgSAE) for the determination of trace amounts of genotoxic substances was demonstrated on the determination of micromolar and submicromolar concentrations of 3-nitrofluoranthene using methanol - 0.01 mol L-1 NaOH ( 9: 1) mixture as a base electrolyte and of Ostazine Orange using 0.01 mol L-1 NaOH as a base electrolyte.
引用
收藏
页码:445 / 452
页数:8
相关论文
共 9 条
  • [1] Modern electrochemical methods for monitoring of chemical carcinogens
    Barek, J
    Moreira, JC
    Zima, J
    [J]. SENSORS, 2005, 5 (4-5) : 148 - 158
  • [2] Voltammetric determination of N,N-dimethyl-4-amine-carboxyazobenzene at a silver solid amalgam electrode
    Barek, J
    Dodova, E
    Navrátil, T
    Yosypchuk, B
    Novotny, L
    Zima, J
    [J]. ELECTROANALYSIS, 2003, 15 (22) : 1778 - 1781
  • [3] Electrochemical methods for monitoring of environmental carcinogens
    Barek, J
    Cvacka, J
    Muck, A
    Quaiserová, V
    Zima, J
    [J]. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 2001, 369 (7-8): : 556 - 562
  • [4] Barek J, 2001, ELECTROANAL, V13, P799, DOI 10.1002/1521-4109(200105)13:8/9<799::AID-ELAN799>3.0.CO
  • [5] 2-C
  • [6] Polarographic and voltammetric determination of chemical carcinogens
    Barek, J
    Mejstrík, V
    Muck, A
    Zima, J
    [J]. CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY, 2000, 30 (01) : 37 - 57
  • [7] Alloy electrodes with high hydrogen overvoltage for analytical use in voltammetry. Some preliminary results
    Mikkelsen, O
    Schroder, KH
    [J]. ANALYST, 2000, 125 (12) : 2163 - 2165
  • [8] Dental amalgam, an alternative electrode material for voltammetric analyses of pollutants
    Mikkelsen, O
    Schroder, KH
    Aarhaug, TA
    [J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2001, 66 (03) : 465 - 472
  • [9] Nontoxic electrodes of solid amalgams
    Yosypchuk, B
    Novotny, L
    [J]. CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY, 2002, 32 (02) : 141 - 151