Two-band system: A candidate for new molecular materials

被引：10

作者：

Kato, R ^{[1
]}

Yamamoto, K ^{[1
]}

Kashimura, Y ^{[1
]}

Okano, Y ^{[1
]}

Aonuma, S ^{[1
]}

机构：

[1] Univ Tokyo, Inst Solid State Phys, Minato Ku, Tokyo 1068666, Japan

来源：

SYNTHETIC METALS | 1999年 / 103卷 / 1-3期

关键词：

organic conductors; organic superconductors; metal-insulator phase transitions; superconducting phase transitions;

D O I：

10.1016/S0379-6779(98)00288-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We describe the two-band system, where two bands with different characters coexist near the Fermi level, as a candidate for new molecular conductors. An interplay of these two bands would provide unique physical properties. (DCNQI)(2)Cu (one-dimensional (1D) LUMO and 3D d(xy) bands), Pd(dmit)(2) salts (1D LUMO and 2D HOMO bands), and (TMET-STF)(2)BF4 (1D HOMO and 2D HOMO bands) would be classified into this two-band system. In the two-band molecular system, new degrees of freedom would be introduced and the tuning of the band-filling would be possible.

引用

页码：2020 / 2023

页数：4

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