Hydrogen repulsion "transition" in Co(OD)2 at high pressure?

被引：51

作者：

Parise, JB ^{[1
]}

Loveday, JS

Nelmes, RJ

Kagi, H

机构：

[1] SUNY Stony Brook, Ctr High Pressure Res, Stony Brook, NY 11794 USA

[2] SUNY Stony Brook, Dept Geosci, Stony Brook, NY 11794 USA

[3] Univ Edinburgh, Dept Phys & Astron, Edinburgh EH9 3JZ, Midlothian, Scotland

[4] Univ Tokyo, Grad Sch Sci, Earthquake Chem Lab, Tokyo 1130033, Japan

来源：

PHYSICAL REVIEW LETTERS | 1999年 / 83卷 / 02期

关键词：

D O I：

10.1103/PhysRevLett.83.328

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Neutron powder diffraction studies of beta-Co(OD)(2) to 16 GPa show that the structural changes with pressure are continuous and reveal no evidence for the amorphization of the hydrogen sublattice at 11 GPa previously proposed on the basis of light-scattering and x-ray diffraction studies [Nyugen et al., Phys. Rev. Lett. 78, 1936 (1997)]. Instead, the changes in the deuterium packing with pressure suggest that the observed anomalies in Raman and infrared data at 11 GPa are the result of structural frustration due to H ... H repulsion.

引用

页码：328 / 331

页数：4

共 32 条

[1] ON H...H DISTANCES AND THE VANDERWAALS RADIUS OF HYDROGEN IN INORGANIC AND ORGANIC-COMPOUNDS [J].

BAUR, WH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1992, 48 :745-746

[2]

BESSON JM, 1992, PHYSICA B, V180, P90

[3]

CATTI M, 1995, PHYS CHEM MINER, V22, P200, DOI 10.1007/BF00202300

[4] Interlayer interactions in M(OH)(2): A neutron diffraction study of Mg(OH)(2) [J].

Desgranges, L ;

Calvarin, G ;

Chevrier, G .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1996, 52 :82-86

[5] HYDROGEN THERMAL MOTION IN CALCIUM HYDROXIDE - CA(OH)2 [J].

DESGRANGES, L ;

GREBILLE, D ;

CALVARIN, G ;

CHEVRIER, G ;

FLOQUET, N ;

NIEPCE, JC .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1993, 49 :812-817

[6]

DUFFY TS, 1995, AM MINERAL, V80, P222

[7]

Hamilton W. C., 1968, HYDROGEN BONDING SOL

[8]

Jeffrey G.A., 1997, An Introduction to Hydrogen Bonding, VVolume 12

[9] VIBRATIONAL-SPECTRA OF MG(OH)2 AND CA(OH)2 UNDER PRESSURE [J].

KRUGER, MB ;

WILLIAMS, Q ;

JEANLOZ, R .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (10) :5910-5915

[10]

LARSON AC, 1986, LAUR86748 LOS AL NAT

← 1 2 3 4 →