Solvation of Carbon Dioxide in [C4mim][BF4] and [C4mim][PF6] Ionic Liquids Revealed by High-Pressure NMR Spectroscopy

被引：63

作者：

Corvo, Marta C. ^{[1
]}

Sardinha, Joao ^{[1
]}

Menezes, Sonia C. ^{[2
]}

Einloft, Sandra ^{[3
]}

Seferin, Marcus ^{[3
]}

Dupont, Jairton ^{[4
]}

Casimiro, Teresa ^{[1
]}

Cabrita, Eurico J. ^{[1
]}

机构：

[1] UNL, REQUIMTE CQFB, Fac Ciencias & Tecnol, Dep Quim, P-2829516 Caparica, Portugal

[2] PETROBRAS CENPES, BR-21941915 Rio De Janeiro, RJ, Brazil

[3] Pontificia Univ Catolica Rio Grande do Sul, Fac Quim, BR-90619900 Porto Alegre, RS, Brazil

[4] Inst Quim UFRGS, Porto Alegre, RS, Brazil

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 49期

关键词：

CO2; sequestration; ionic liquids; molecular dynamics; NMR spectroscopy; 1-BUTYL-3-METHYLIMIDAZOLIUM ACETATE; RAMAN-SPECTROSCOPY; LOCAL-STRUCTURE; HYDROGEN-BONDS; CO2; CAPTURE; ORGANIZATION; SOLUBILITY;

D O I：

10.1002/anie.201305630

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Where is CO2? The intermolecular interactions of [C 4mim]BF4 and [C4mim]PF6 ionic liquids and CO2 have been determined by high-pressure NMR spectroscopy in combination with molecular dynamic simulations. The anion and the cation are both engaged in interactions with CO2. A detailed picture of CO2 solvation in these ILs is provided. CO2 solubility is essentially determined by the microscopic structure of the IL. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13024 / 13027

页数：4

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