Dirhodium (II) carboxylate-catalysed oxidation of allylic and benzylic alcohols

被引：18

作者：

Moody, CJ ^{[1
]}

Palmer, FN ^{[1
]}

机构：

[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(01)02048-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylic and benzylic alcohols are oxidised to the corresponding carbonyl compounds using tert-butyl hydroperoxide. preferably in stoichiometric amounts, and dirhodium(II) tetraacetate as catalyst (1 mol%) in dichloromethane at ambient temperature. (C) 2001 Elsevier Science Ltd. All rights reserved.

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页码：139 / 141

页数：3

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