Diastereoselective synthesis of heterosubstituted organogembismetallic reagents. Application to a new propargylmetalation reaction of vinyl metals.

被引：38

作者：

Brasseur, D ^{[1
]}

Marek, I ^{[1
]}

Normant, JF ^{[1
]}

机构：

[1] UNIV PARIS 06,LAB CHIM ORGANOELEMENTS,CNRS,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON | 1996年 / 52卷 / 21期

关键词：

D O I：

10.1016/0040-4020(96)00248-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The allylzincation and propargylzincation of various gamma-heterosubstituted vinyl metals proceed diastereoselectively. This represents a new synthetic approach to construct two or three adjacent stereogenic centers in acyclic systems. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：7235 / 7250

页数：16

共 28 条

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