Atmosphere generation system for the preparation of ambient air volatile organic compound standard mixtures

被引:21
作者
Ballesta, PP [1 ]
Baldan, A [1 ]
Cancelinha, J [1 ]
机构
[1] Commiss European Communities, Joint Res Ctr, Inst Environm, Ispra Estab, I-21020 Ispra, VA, Italy
关键词
D O I
10.1021/ac981291l
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A dynamic generation system based on permeation for the preparation of volatile organic compounds at ambient air concentration levels is described herein. The performance of the equipment, sources of uncertainties, and overall uncertainty value are also evaluated. The system is capable of generating multicomponent mixtures at ppb levels and simulating different atmospheric conditions by changing the humidity, concentration level, temperature, and wind velocity. A minimized value for the overall uncertainty in the concentration generated by the system was determined to be +/-1.9% for higher weighing time intervals of 4 weeks.
引用
收藏
页码:2241 / 2245
页数:5
相关论文
共 21 条
[1]  
BROWN RH, 1984, AM IND HYG ASSOC J, V45, P67
[2]  
CASSINELLI ME, 1987, DIFFUSIVE SAMPLING A, P190
[3]  
*CEN EN, 1995, 838 CEN EN
[4]  
*CEN TC, 26411 CENTC
[5]  
DENNIS JE, 1981, ACM T MATH SOFTWARE, V7, P348, DOI 10.1145/355958.355965
[6]  
DIETRICH O, 1991, UNCERTAINTY CALIBRAT, P248
[7]   DIFFUSION APPARATUS FOR TRACE LEVEL VAPOR GENERATION OF TETRAMETHYLLEAD [J].
FIELDEN, PR ;
GREENWAY, GM .
ANALYTICAL CHEMISTRY, 1989, 61 (17) :1993-1996
[8]   DEVELOPMENT AND PERFORMANCE-CHARACTERISTICS OF A CAPILLARY DOSAGE UNIT WITH INSITU WEIGHT SENSOR FOR THE PREPARATION OF KNOWN AMOUNTS OF GASEOUS VOCS IN AIR [J].
GOELEN, E ;
LAMBRECHTS, M ;
GEYSKENS, F ;
RYMEN, T .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 1992, 47 (04) :217-225
[9]  
GOSJEAN D, 1992, ATMOS ENVIRON A-GEN, V26, P2923
[10]  
HORL H, 1993, ENVIRON SCI TECHNOL, V27, P2023