Indium triflate: a reusable catalyst for expeditious chemoselective conversion of aldehydes to acylals

被引：70

作者：

Ghosh, R ^{[1
]}

Maiti, S ^{[1
]}

Chakraborty, A ^{[1
]}

Haider, R ^{[1
]}

机构：

[1] Jadavpur Univ, Dept Chem, Kolkata 700032, W Bengal, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 215卷 / 1-2期

关键词：

indium triflate; catalysed; chemoselective; acylal;

D O I：

10.1016/j.molcata.2004.01.018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A mild, efficient and expeditious method has been developed for the chemoselective conversion of aldehydes to the corresponding acylals in excellent yields, using acetic anhydride in the presence of catalytic amount (0.01-0.1 mol%) of In(OTf)(3). Ketones remain unaffected under the reaction condition. In(OTf)(3) can be recovered and reused without any loss of its catalytic activity. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：49 / 53

页数：5

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