Organoantimony oxides: Preparation and crystal structures of [(2-PhOC6H4)O(C6H4)(2)Sb](2)O-2 and (o-Tol(2)Sb)(4)O-6

被引：11

作者：

Breunig, HJ ^{[1
]}

Probst, J ^{[1
]}

Ebert, KH ^{[1
]}

Lork, E ^{[1
]}

CeaOlivares, R ^{[1
]}

AlvaradoRodriguez, JG ^{[1
]}

机构：

[1] NATL AUTONOMOUS UNIV MEXICO,INST QUIM,MEXICO CITY 04510,DF,MEXICO

来源：

CHEMISCHE BERICHTE-RECUEIL | 1997年 / 130卷 / 07期

关键词：

phenoxystibanes; organoantimony oxides; antimony; main group elements;

D O I：

10.1002/cber.19971300724

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Air oxidation of (Oxydi-2,1-phenylene)(2-phenoxyphenyl)stibane (1) gives the phenoxystibane oxide [(2-PhO-C6H4)O(C6H4)(2)Sb](2)O-2(2). Single crystals of (o-Tol(2)Sb)(4)-O-4(O-2)(2) (3) were obtained by air oxidation of o-TolSb-(SiMe3)(2). Crystal structures of 2 and 3 are reported.

引用

页码：959 / 961

页数：3

共 13 条

[1] CRYSTAL-STRUCTURE OF 2,2,4,4-TETRAHYDRO-2,2,2,4,4,4-HEXAPHENYL-1,3,2,4-DIOXADISTIBETANE (TRIPHENYLSTIBINE OXIDE DIMER) AND RELATED-COMPOUNDS [J].

BORDNER, J ;

DOAK, GO ;

EVERETT, TS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (14) :4206-4213

[2]

Breunig H. J., 1997, ANGEW CHEM, V109, P654

[3] A mu(4)-peroxo complex of antimony: Synthesis and structure of (o-Tol(2)SbO)(4)(O-2)(2) [J].

Breunig, HJ ;

Kruger, T ;

Lork, E .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (06) :615-617

[4] SYNTHESIS AND CRYSTAL-STRUCTURE OF (PHSB)6.1,4-DIOXANE, (PHSB)6IBANES [J].

BREUNIG, HJ ;

SOLTANINESHAN, A ;

HABERLE, K ;

DRAGER, M .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1986, 41 (03) :327-333

[5] SYNTHESES, STRUCTURES, AND EQUILIBRIA OF O-TOLYLANTIMONY, M-TOLYLANTIMONY, P-TOLYLANTIMONY AND PHENYLANTIMONY RINGS [J].

BREUNIG, HJ ;

EBERT, KH ;

GULEC, S ;

PROBST, J .

CHEMISCHE BERICHTE, 1995, 128 (06) :599-603

[6] SYNTHESIS AND CHARACTERIZATION OF PHENOXARSIN-10-YL 2-R(2)N-CYCLOPENT-1-ENE-1-CARBODITHIOATE (R=H, C2H5 CYCLO-C6H11CH2) AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF THE 2-AMINO (R=H) DERIVATIVE [J].

CEAOLIVARES, R ;

TOSCANO, RA ;

ESTRADA, M ;

SILVESTRU, C ;

GARCIA, PGY ;

LOPEZCARDOSO, M ;

BLASSAMADOR, G .

APPLIED ORGANOMETALLIC CHEMISTRY, 1995, 9 (02) :133-140

[7]

CEAOLIVARES R, IN PRESS INORG CHIM

[8]

CORDES AW, 1972, INORG CHEM, V11, P1849

[9]

CORDES AW, 1983, ACTA CRYSTALLOGR S C, V39, P709

[10] IMPROVED PROCEDURE FOR DIMETALATION OF DIPHENYL ETHER [J].

GILMAN, H ;

TREPKA, WJ .

JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (12) :5202-&

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