Melting of LiF and NaCl to 1 Mbar: Systematics of ionic solids at extreme conditions

被引:158
作者
Boehler, R [1 ]
Ross, M [1 ]
Boercker, DB [1 ]
机构
[1] LAWRENCE LIVERMORE NATL LAB,LIVERMORE,CA 94551
关键词
D O I
10.1103/PhysRevLett.78.4589
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We report the first diamond cell data for the melting curves of LIF and NaCl up to 1 Mbar (100 GPa). The melting curve of NaCl is in agreement with shock data and shows a break in slope at 290 kbar due to the B1(NaCl)-B2(CsCl) transition. LiF remains B1 to the highest pressure, and molecular dynamic simulations predict that molten LIF retains a simple-cubic B1-like structure. A plot of the recent Mainz diamond anvil melting curves for MgO, LiF, KBr, KCI, CsI, and NaCl shows that at very high pressure all the melting curves have very similar slopes approaching a value of order 1-2 K/kbar.
引用
收藏
页码:4589 / 4592
页数:4
相关论文
共 27 条