Shear viscosity of nylon 6 melts reinforced with microfibrous calcium silicate hydrate

被引:19
作者
Tanaka, H [1 ]
Watanabe, K [1 ]
机构
[1] Ube Ind Ltd, Polymer Lab, Yamaguchi 7558633, Japan
关键词
D O I
10.1002/pen.11469
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Steady shear viscosity of nylon 6 melts reinforced with xonotlite, microfibrous calcium silicate hydrate (6CaO . 6SiO(2) . H2O), is investigated. The highly filled nylon 6 melt tends to exhibit a yield value, resulting in remarkable viscosity increase particularly at low shear rates. Addition of the xonotlite significantly increases activation energy of viscous flow of the nylon 6 melt, leading the viscosity to be strongly temperature dependent. Comparisons with the melts filled with glass fibers and wollastonite are made. Flow-induced orientation becomes more important at low volume fractions. Shortening of the xonotlite during shear flow measurement can also be observed.
引用
收藏
页码:817 / 824
页数:8
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