4-(Trifluoromethyl)benzonitrile

被引：9

作者：

Boitsov, S ^{[1
]}

Songstad, J ^{[1
]}

Törnroos, KW ^{[1
]}

机构：

[1] Univ Bergen, Dept Chem, N-5007 Bergen, Norway

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷

关键词：

D O I：

10.1107/S0108270101019540

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

4-(Trifluoromethyl)benzonitrile, C8H4F3N, at 123 K contains molecules linked together through one C-H...F bond and two C-H...N hydrogen bonds into sheets that are further crosslinked to form a dense two-dimensional network without pi...pi ring interactions. The aromatic ring is slightly deformed due to the two para-related electronegative groups.

引用

收藏

页码：o66 / o68

页数：3

相关论文

共 21 条

[1] THE CONFORMATION OF 2-FLUOROETHANOL - IS INTRAMOLECULAR HYDROGEN-BONDING IMPORTANT [J].

BAKKE, JM ;

BJERKESETH, LH ;

RONNOW, TECL ;

STEINSVOLL, K .

JOURNAL OF MOLECULAR STRUCTURE, 1994, 321 (03) :205-214

[2] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[3]

*BRUK AXS INC, 2001, SAINT VERS 6 02A

[4]

*BRUK AXS INC, 1999, SMART VERS 5 054

[5] MOLECULAR-STRUCTURE AND RING DISTORTIONS OF PARA-DICYANOBENZENE IN THE GAS-PHASE AND IN THE CRYSTAL [J].

COLAPIETRO, M ;

DOMENICANO, A ;

PORTALONE, G ;

SCHULTZ, G ;

HARGITTAI, I .

JOURNAL OF MOLECULAR STRUCTURE, 1984, 112 (1-2) :141-157

[6]

Desiraju G. R., 1999, The Weak Hydrogen Bond

[7] CONFORMATIONAL ENERGIES OF 2-FLUOROETHANOL AND 2-FLUOROACETALDEHYDE ENOL - STRENGTH OF THE INTERNAL HYDROGEN-BOND [J].

DIXON, DA ;

SMART, BE .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (04) :1609-1612

[8] Hydrogen bonding in DNA - a return to the status quo [J].

Evans, TA ;

Seddon, KR .

CHEMICAL COMMUNICATIONS, 1997, (21) :2023-2024

[9]

HINE J, 1962, PHYSICAL ORGANIC CHE

[10]

Hiyama T., 2000, ORGANOFLUORINE COMPO, DOI DOI 10.1007/978-3-662-04164-2