Electrochemical lithium ion storage properties of single-walled carbon nanotubes containing organic molecules

被引：27

作者：

Kawasaki, S. ^{[1
]}

Iwai, Y. ^{[1
]}

Hirose, M. ^{[1
]}

机构：

[1] Nagoya Inst Technol, Grad Sch Engn, Dept Mat Sci & Engn, Showa Ku, Nagoya, Aichi 4668555, Japan

来源：

CARBON | 2009年 / 47卷 / 04期

关键词：

D O I：

10.1016/j.carbon.2008.12.034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Li ion storage properties of single-walled carbon nanotube peapods containing one of three organic molecules (9,10-dichloroanthracene, beta-carotene, coronene) were measured. It was found by electrochemical charge-discharge measurements that the reversible storage capacity of the SWCNTs significantly increased as a result of the inclusion, although unfortunately the samples are still not appropriate for the practical use as an anode material in Li ion battery because of the high irreversible capacity (>900 mAh/g). In the most effective case, the tube containing the organic molecule can store about 2.5 times more Li ions compared to an empty tube. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1081 / 1086

页数：6

共 13 条

[1] Electrochemical doping of single wall carbon nanotubes with lithium [J].

Claye, A ;

Fischer, JE .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2000, 340 :743-748

[2] Solid-state electrochemistry of the Li single wall carbon nanotube system [J].

Claye, AS ;

Fischer, JE ;

Huffman, CB ;

Rinzler, AG ;

Smalley, RE .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (08) :2845-2852

[3] Electrochemical storage of lithium multiwalled carbon nanotubes [J].

Frackowiak, E ;

Gautier, S ;

Gaucher, H ;

Bonnamy, S ;

Beguin, F .

CARBON, 1999, 37 (01) :61-69

[4] Enhanced saturation lithium composition in ball-milled single-walled carbon nanotubes [J].

Gao, B ;

Bower, C ;

Lorentzen, JD ;

Fleming, L ;

Kleinhammes, A ;

Tang, XP ;

McNeil, LE ;

Wu, Y ;

Zhou, O .

CHEMICAL PHYSICS LETTERS, 2000, 327 (1-2) :69-75

[5] SINGLE-SHELL CARBON NANOTUBES OF 1-NM DIAMETER [J].

IIJIMA, S ;

ICHIHASHI, T .

NATURE, 1993, 363 (6430) :603-605

[6] HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].

IIJIMA, S .

NATURE, 1991, 354 (6348) :56-58

[7]

KAWASAKI S, MAT RES B IN PRESS

[8] Phase diagram of interacting composite fermions in the bilayer ν=2/3 quantum Hall effect -: art. no. 116802 [J].

Kumada, N ;

Terasawa, D ;

Shimoda, Y ;

Azuhata, H ;

Sawada, A ;

Ezawa, ZF ;

Muraki, K ;

Saku, T ;

Hirayama, Y .

PHYSICAL REVIEW LETTERS, 2002, 89 (11)

[9] SEI layer-forming additives for LiNi0.5Mn1.5O4/graphite 5 VLi-ion batteries [J].

Lee, Hochun ;

Choi, Seungdon ;

Choi, Sanghoon ;

Kim, Hyeong-Jin ;

Choi, Yongsu ;

Yoon, Soojin ;

Cho, Jeong-Ju .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (04) :801-806

[10] Single wall carbon nanotube paper as anode for lithium-ion battery [J].

Ng, SH ;

Wang, J ;

Guo, ZP ;

Wang, GX ;

Liu, HK .

ELECTROCHIMICA ACTA, 2005, 51 (01) :23-28

← 1 2 →