Improved chemoselective, ecofriendly conditions for the conversion of primary alkyl halides into nitroalkanes under PEG400

被引：36

作者：

Ballini, Roberto ^{[1
]}

Barboni, Luciano ^{[1
]}

Palmieri, Alessandro ^{[1
]}

机构：

[1] Univ Camerino, Dipartimento Sci Chim, Via S Agostino 1, I-62032 Camerino, Italy

来源：

GREEN CHEMISTRY | 2008年 / 10卷 / 09期

关键词：

D O I：

10.1039/b805985c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of primary alkyl bromides or iodides with 1.5-3 equivalents of sodium nitrite, at room temperature, in PEG400 as solvent, allows the chemoselective formation of primary nitroalkanes in satisfactory to good yields, under ecofriendly reaction conditions.

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收藏

页码：1004 / 1006

页数：3

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