Application of the Rotating Ring-Disc-Electrode Technique to Water Oxidation by Surface-Bound Molecular Catalysts

被引：43

作者：

Concepcion, Javier J. ^{[1
]}

Binstead, Robert A. ^{[1
]}

Alibabaei, Leila ^{[1
]}

Meyer, Thomas J. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27514 USA

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 19期

关键词：

PHOTOSYSTEM-II; IRIDIUM COMPLEXES; SINGLE-SITE; DIMER; ASSEMBLIES; MECHANISM;

D O I：

10.1021/ic402240t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report here the application of a simple hydrodynamic technique, linear sweep voltammetry with a modified rotating-ring-disc electrode, for the study of water oxidation catalysis. With this technique, we have been able to reliably obtain turnover frequencies, over-potentials, Faradaic conversion efficiencies, and mechanistic information from single samples of surface-bound metal complex catalysts.

引用

页码：10744 / 10746

页数：3

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