The two component palladium catalyst system for intermolecular hydroamination of allenes

被引:117
作者
AlMasum, M
Meguro, M
Yamamoto, Y
机构
[1] INST CHEM REACT SCI,RES CTR ORGAN RESOURCES & MAT CHEM,SENDAI,MIYAGI 98077,JAPAN
[2] TOHOKU UNIV,GRAD SCH SCI,DEPT CHEM,SENDAI,MIYAGI 98077,JAPAN
关键词
D O I
10.1016/S0040-4039(97)01370-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The combination of acetic acid with Pd-2(dba)(3).CHCl3 and dppf [1.1(1)-Bis(diphenylphosphino ferrocene)] is a new type of catalytic system, capable of effecting the addition of protected and/or functionalized amines to allenes with high regio- and stereoselectivity. (C) 1997 Elsevier Science Ltd.
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页码:6071 / 6074
页数:4
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