Synthesis of isotopically labeled zinc methyl bacteriopheophorbide-D as a model for light-harvesting antenna pigments

被引：12

作者：

Tamiaki, H

Shimono, Y

Rattray, AGM

Tanikaga, R

机构：

[1] Department of Bioscience and Biotechnology, Faculty of Science and Engineering, Ritsumeikan University, Kusatsu

来源：

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS | 1996年 / 6卷 / 17期

关键词：

D O I：

10.1016/0960-894X(96)00380-0

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Grignard reaction of methyl pyropheophorbide-d (1) possessing a 3-formyl group with methyl magnesium iodide selectively gave methyl bacteriopheophorbide-d (2) possessing a 3-(1-hydroxyethyl) group. When (CH3MgI)-C-13 and CD3MgI were used as the Grignard reagents, specifically labeled 2 were afforded, of which zinc complexes 3 serve as model compounds for natural bacteriochlorophylls-d. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2085 / 2086

页数：2

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