Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon-carbon bond formation

被引：30

作者：

Daniel, Marion ^{[1
,2
]}

Fensterbank, Louis ^{[1
,2
]}

Goddard, Jean-Philippe ^{[1
,2
,3
]}

Ollivier, Cyril ^{[1
,2
]}

机构：

[1] Univ Paris 06, Sorbonne Univ, Inst Parisien Chim Mol, UMR 8232, F-75005 Paris, France

[2] CNRS, UMR 8232, Inst Parisien Chim Mol, F-75005 Paris, France

[3] Univ Haute Alsace, Lab Chim Organ & Bioorgan, Ecole Natl Super Chim Mulhouse, EA 4566, F-68093 Mulhouse, France

来源：

ORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 05期

关键词：

FREE-RADICAL CYCLIZATIONS; PHOTOREDOX CATALYSIS; ELECTRON-TRANSFER; FORMING REACTIONS; ORGANIC-SYNTHESIS; SYNTHETIC APPLICATIONS; PSCHORR REACTION; SULFONIUM SALTS; DIAZONIUM SALTS; EXCITED-STATES;

D O I：

10.1039/c4qo00071d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds, using Ru(bpy)(3)Cl-2 as a photocatalyst and combining molecular oxygen and triphenylcarbenium as a new sacrificial acceptor, has been developed for carbon-carbon bond formation giving access to dimerization, allylation and polycyclization products.

引用

页码：551 / 555

页数：5

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