Carboxylates as pronucleophiles in the phosphine-catalyzed γ-addition reaction

被引：31

作者：

Alvarez-Ibarra, C ^{[1
]}

Csáky, AG ^{[1
]}

de la Oliva, CG ^{[1
]}

机构：

[1] Univ Complutense, Fac Quim, Dept Quim Organ 1, E-28040 Madrid, Spain

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 48期

关键词：

addition reaction; carboxylic acids; carboxylic acid derivatives; phosphines; sodium; sodium compounds;

D O I：

10.1016/S0040-4039(99)01775-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carboxylates have been used as pronucleophiles in the phosphine-catalyzed gamma-addition reaction to alkynes bearing electron-withdrawing groups (Trost's reaction) giving rise to functionalized allyl carboxylates. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：8465 / 8467

页数：3

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