Halogen-free process for the conversion of carbon dioxide to urethanes by homogeneous catalysis

被引：122

作者：

Abla, M ^{[1
]}

Choi, JC ^{[1
]}

Sakakura, T ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 21期

关键词：

D O I：

10.1039/b106201h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon dioxide is converted to urethanes (carbamic acid derivatives) through reaction with amine and alcohol catalyzed by tin complexes; the addition of acetals as a dehydrating agent under high CO2 pressure is the key to achieve high yields.

引用

页码：2238 / 2239

页数：2

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