Dendritic liquid-crystalline fullerene-ferrocene dyads

被引：44

作者：

Campidelli, S

Pérez, L

Rodríguez-López, J

Barberá, J

Langa, F

Deschenaux, R

机构：

[1] Univ Castilla La Mancha, Fac Ciencias Medio Ambiente, Toledo 45071, Spain

[2] Univ Neuchatel, Inst Chim, CH-2007 Neuchatel, Switzerland

[3] Univ Zaragoza, CSIC, Fac Ciencias, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

来源：

TETRAHEDRON | 2006年 / 62卷 / 09期

关键词：

ferrocene; fullerene; supramolecular organization;

D O I：

10.1016/j.tet.2005.10.065

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

First- and second-generation ferrocene-based dendrimers, fullerene and a second-generation liquid-crystal line poly(arylester) dendrimer carrying four cyanobiphenyl units were assembled to elaborate polyfunctional materials displaying mesomorphic and electronic properties. The targeted compounds gave rise to enantiotropic smectic A phases and organized into bilayer structures within the smectic layers. Cyclic voltammetry investigations revealed oxidation and reduction processes in agreement with the presence of both ferrocene and fullerene units. Finally, strong quenching of the fluorescence was obtained for the fullerene-ferrocene dyads suggesting efficient elecron transfer from the ferrocene-based dendrimer to fullerene. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：2115 / 2122

页数：8

共 39 条

[1] Effective recognition of H2PO4- by a new series of dendrimers functionalized with ferrocenyl-urea termini [J].