Topochemical polymerization of naphthalenediimide-substituted diacetylene suspensions

被引：20

作者：

Koehorst, RBM

Fokkink, RG

Stuart, MC

Zuilhof, H

Sudhölter, EJR

机构：

[1] Univ Wageningen & Res Ctr, Organ Chem Lab, NL-6703 HB Wageningen, Netherlands

[2] Univ Wageningen & Res Ctr, Lab Phys Chem & Colloid Sci, NL-6703 HB Wageningen, Netherlands

来源：

MACROMOLECULES | 2002年 / 35卷 / 11期

关键词：

D O I：

10.1021/ma012088m

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An overview is given on the solution-phase polymerization of aggregates of naphthalenediimide-substituted diacetylenes. It is shown that the mechanism of formation of this polymer may involve radical cations as the primary species, formed by photoinduced electron transfer from a DA donor to a photoexcited, covalently linked naphthalenediimide electron acceptor.

引用

页码：4226 / 4228

页数：3

共 39 条

[1]

ALBRECHT C, 1993, PROG COLL POL SCI S, V92, P111

[2] Polymerization of modified diacetylenes in Langmuir films [J].