Electron spin resonance absorption in organic metal polyaniline and its blend with PMMA

被引:18
作者
Srinivasan, D
Natarajan, TS
Rangarajan, G [1 ]
Bhat, SV
Wessling, B
机构
[1] Indian Inst Technol, Dept Phys, Madras 600036, Tamil Nadu, India
[2] Indian Inst Sci, Dept Phys, Bangalore 560012, Karnataka, India
[3] Ormecon Chem GMBH & Co KG, D-22926 Ahrensburg, Germany
关键词
disordered systems; polymers; elastomers and plastics; electronic transport; spin dynamics; electron paramagnetic resonance;
D O I
10.1016/S0038-1098(99)00109-X
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The electron spin resonance absorption in the synthetic metal polyaniline (PANI) doped with PTSA and its blend with poly(methylmethacrylate) (PMMA) is investigated in the temperature range between 4.2 and 300 K. The observed line shape follows Dyson's theory for a thick metallic plate with slowly diffusing magnetic dipoles. At low temperatures the line shape become symmetric and Lorentzian when the sample dimensions are small in comparison with the skin depth. The temperature dependence of electron spin relaxation time is discussed. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:503 / 508
页数:6
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