[CpAlN(2,6-i-Pr2C6H3)](2): A dimeric iminoalane obtained by alkane elimination

被引：51

作者：

Fisher, JD

Shapiro, PJ

Yap, GPA

Rheingold, AL

机构：

[1] UNIV IDAHO,DEPT CHEM,MOSCOW,ID 83844

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 02期

关键词：

D O I：

10.1021/ic951201k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimeric iminoalane, [CpAlN(2,6-i-Pr2C6H3)](2) (2), has been prepared from a double dealkylation reaction between Cp(3)Al and 2,6-diisopropylaniline. The single-crystal X-ray structure of 2 reveals a nearly square planar Al2N2 Core, with each cyclopentadienyl ring coordinated to its aluminum atom in a pentahapto fashion. This structure represents the first solid-state characterization of an eta(5)-coordination geometry between a simple C5H5 ring and aluminum.

引用

收藏

页码：271 / &

页数：3

相关论文

共 46 条

[1] COMPLEXES OF ORGANOALUMINUM COMPOUNDS .7. PREPARATION AND SPECTRA OF CIS-CYCLOTRI-MU-METHYLAMIDO-TRIS(DIMETHYLALUMINIUM) AND TRANS-CYCLOTRI-MU-METHYLAMIDO-TRIS(DIMETHYL-ALUMINIUM) AND SOME RELATED COMPOUNDS [J].

ALFORD, KJ ;

SMITH, JD ;

GOSLING, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (20) :2203-&

[2] COMPLEXES OF ORGANOALUMINUM COMPOUNDS .13. PREPARATION AND NUCLEAR MAGNETIC-RESONANCE SPECTRA OF THE ARYLAMIDO-COMPOUNDS ALME2(NHPH), ALME2(NHC6H4ME-O), ALME2(NHC6H4ME-P), ALME2(NHC6H3ME2-2), ALME2(NH6) AND THE IMIDO-COMPOUNDS AIME(NR') - CRYSTAL AND MOLECULAR-STRUCTURES OF [(ALME2(NHC6H4ME-O))2] AND [(ALME(NPH))6]4 [J].

ALWASSIL, AAI ;

HITCHCOCK, PB ;

SARISABAN, S ;

SMITH, JD ;

WILSON, CL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (09) :1929-1934

[3] COMPLEXES OF ORGANOALUMINUM COMPOUNDS .10. CRYSTAL AND MOLECULAR-STRUCTURES OF THE CAGE COMPOUNDS BIS-MU-METHYLAMIDO-HEXA-MU-3-METHYLIMIDO-BIS(DIMETHYLALUMINIUM)-HEXAKIS(METHYLALUMINIUM) AND BIS-MU-METHYLAMIDO-HEXA-MU-3-METHYLIMIDO-BIS(DIMETHYLGALLIUM)-HEXAKIS-(METHYLGALLIUM) [J].

AMIRKHALILI, S ;

HITCHCOCK, PB ;

SMITH, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (07) :1206-1212

[4] STEREOCHEMISTRY OF POLYNUCLEAR COMPOUNDS OF MAIN GROUP ELEMENTS .12. PREPARATION AND STRUCTURE OF ETHYLENIMINODIMETHYLALUMINUM TRIMER [J].

ATWOOD, JL ;

STUCKY, GD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (02) :285-&

[5] THEORETICAL INVESTIGATION OF ALUMINUM OXYGEN PI-BONDING IN 3-COORDINATE AND 4-COORDINATE ALUMINUM ALKOXIDES [J].

BARRON, AR ;

DOBBS, KD ;

FRANCL, MM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) :39-43

[6] SYNTHESIS AND CHARACTERIZATION OF (PENTAFLUOROPHENYL)AMINO-BASED AMINOMETALLANES AND IMINOMETALLANES - CRYSTAL-STRUCTURES OF (MEALNC(6)F(5))(4) AND NHC6F5GA(MESGA)(3)(MU-3NC6F5)(4) (MES=2,4,6-ME(3)C(6)H(2)) [J].

BELGARDT, T ;

WAEZSADA, SD ;

ROESKY, HW ;

GORNITZKA, H ;

HAMING, L ;

STALKE, D .

INORGANIC CHEMISTRY, 1994, 33 (26) :6247-6251

[7] CHEMISTRY AND STEREOCHEMISTRY OF POLY(N-ALKYL-IMINOALANES) .2. CRYSTAL AND MOLECULAR-STRUCTURE OF HEXAMER, (HAIN-I-PR)6 [J].

CESARI, M ;

PEREGO, G ;

DELPIERO, G ;

CUCINELL.S ;

CERNIA, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 78 (02) :203-213

[8] CHEMISTRY AND STEREOCHEMISTRY OF POLY(N-ALKYL-IMINOALANES) .1. SYNTHESIS AND PHYSICOCHEMICAL CHARACTERIZATION OF POLY(N-ALKYLIMINOALANES) [J].

CUCINELLA, S ;

SALVATOR.T ;

BUSETTO, C ;

PEREGO, G ;

MAZZEI, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 78 (02) :185-201

[9]

DELPY K, 1984, Z NATURFORSCH B, V39, P1696

[10] ON A DIAZADIBORETIDINE AS 4-ELECTRON DONOR AGAINST CHROMIUM AND TUNGSTEN [J].

DELPY, K ;

SCHMITZ, D ;

PAETZOLD, P .

CHEMISCHE BERICHTE-RECUEIL, 1983, 116 (08) :2994-2999

← 1 2 3 4 5 →