Aqueous solubilization of crystalline fullerenes by supramolecular complexation with γ-cyclodextrin and sulfocalix[8]arene under mechanochemical high-speed vibration milling

被引：145

作者：

Komatsu, K ^{[1
]}

Fujiwara, K

Murata, Y

Braun, T

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

[2] Eotvos Lorand Univ, Dept Inorgan & Analyt Chem, H-1143 Budapest, Hungary

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1999年 / 20期

关键词：

D O I：

10.1039/a904736k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The solid-state supramolecular complexation of fullerenes C(60) and C(70) as well as some derivatives of C(60) was attained with gamma-cyclodextrin by the use of a mechanochemical high-speed vibration milling technique. Similarly C(60) and the fullerene dimer C(120) were complexed with sulfocalix[8]arene. The complexes produced were found to be soluble in water, and their solubility was examined by UV-vis spectroscopy.

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页码：2963 / 2966

页数：4

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