ZnS-Graphene nanocomposite: Synthesis, characterization and optical properties

被引:97
作者
Pan, Shugang [1 ]
Liu, Xiaoheng [1 ]
机构
[1] Nanjing Univ Sci & Technol, Minist Educ, Key Lab Soft Chem & Funct Mat, Nanjing 210094, Jiangsu, Peoples R China
关键词
Graphene; ZnS; Nanocomposite; SERS; Fluorescence enhancement; ENHANCED RAMAN-SPECTROSCOPY; EXFOLIATED GRAPHITE OXIDE; QUANTUM DOTS; SEMICONDUCTOR PHOTOCATALYSIS; MOLECULAR PRECURSOR; CHEMICAL-REDUCTION; POLYMER COMPOSITES; NANOPARTICLES; PHOTOLUMINESCENCE; NANOCRYSTALS;
D O I
10.1016/j.jssc.2012.02.048
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A ZnS-Graphene nanocomposite was prepared by a facile one-step hydrothermal method using zinc nitrate hexahydrate, ethylenediamine and carbon disulfide as precursors, graphene oxide as a template. The composite was characterized by X-ray power diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, Fourier transform infrared, Raman spectra and fluorescence spectroscopy. The results show that graphene oxide was reduced to graphene in the hydrothermal reaction process. Simultaneously, the graphene sheets in the composite are exfoliated and decorated with ZnS nanoparticles. Furthermore, Raman and fluorescence properties of the composite were observed. ZnS-Graphene nanocomposite displays surface-enhanced Raman scattering activity for graphene oxide, and fluorescence enhancement property compared with pure ZnS sample. (C) 2012 Elsevier Inc. All rights reserved.
引用
收藏
页码:51 / 56
页数:6
相关论文
共 54 条
[1]   PHOTO-LUMINESCENCE AND PHOTOINDUCED OXYGEN-ADSORPTION OF COLLOIDAL ZINC-SULFIDE DISPERSIONS [J].
BECKER, WG ;
BARD, AJ .
JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (24) :4888-4893
[2]   Luminescence quenching in ZnS nanoparticles due to Fe and Ni doping [J].
Borse, PH ;
Deshmukh, N ;
Shinde, RF ;
Date, SK ;
Kulkarni, SK .
JOURNAL OF MATERIALS SCIENCE, 1999, 34 (24) :6087-6093
[3]   Graphite oxide:: Chemical reduction to graphite and surface modification with primary aliphatic amines and amino acids [J].
Bourlinos, AB ;
Gournis, D ;
Petridis, D ;
Szabó, T ;
Szeri, A ;
Dékány, I .
LANGMUIR, 2003, 19 (15) :6050-6055
[4]   QUANTUM CRYSTALLITES AND NONLINEAR OPTICS [J].
BRUS, L .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1991, 53 (06) :465-474
[5]   Preparation of fully exfoliated graphite oxide nanoplatelets in organic solvents [J].
Cai, Dongyu ;
Song, Mo .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (35) :3678-3680
[6]   Effects of cosurfactant on ZnS nanoparticle synthesis in microemulsion [J].
Charinpanitkul, T ;
Chanagul, A ;
Dutta, J ;
Rungsardthong, U ;
Tanthapanichakoon, W .
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2005, 6 (3-4) :266-271
[7]   Differential growth and photoluminescence of ZnS nanocrystals with variation of surfactant molecules [J].
Chatterjee, Anindita ;
Priyam, Amiya ;
Bhattacharya, Subhash C. ;
Saha, Abhijit .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 297 (1-3) :258-266
[8]   Single-walled carbon nanotube networks decorated with silver nanoparticles: A novel graded SERS substrate [J].
Chen, Yi-Chieh ;
Young, Robert J. ;
Macpherson, Julie V. ;
Wilson, Neil R. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (44) :16167-16173
[9]   LUMINESCENCE AND PHOTOPHYSICS OF CDS SEMICONDUCTOR CLUSTERS - THE NATURE OF THE EMITTING ELECTRONIC STATE [J].
CHESTNOY, N ;
HARRIS, TD ;
HULL, R ;
BRUS, LE .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (15) :3393-3399
[10]  
COLVIN VL, 1994, NATURE, V370, P354, DOI 10.1038/370354a0