5,5′-bis(trimethylsilylethynyl)-2,2′-bipyridine

被引:7
作者
Khan, MS
Ahrens, B
Male, L
Raithby, PR
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Sultan Qaboos Univ, Coll Sci, Dept Chem, Al Khoud 123, Oman
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷
关键词
D O I
10.1107/S1600536804010128
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, 5,5'-bis(trimethylsilylethynyl)-2,2'-bipyridine, C20H24N2Si2, is a trimethylsilyl-protected dialkyne. It is a precursor in the preparation of platinum di-yne complexes and platinum poly-yne polymers. Such organic compounds are of interest because of the extended pi-conjugation that occurs through the hetero-aromatic linker unit in the molecular backbone. Within the molecule, the silyl-alkyne groups are essentially linear and the bipyridine unit is approximately planar with a dihedral angle of 5.3 (1)degrees between the planes.
引用
收藏
页码:O915 / O916
页数:2
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