Dendralene-type TTF vinylogs containing a 1,3-diselenole ring

被引:29
作者
Amaresh, RR [1 ]
Liu, DZ [1 ]
Konovalova, T [1 ]
Lakshmikantham, MV [1 ]
Cava, MP [1 ]
Kispert, LD [1 ]
机构
[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
关键词
D O I
10.1021/jo010663e
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
2-Diformylmethylene-1,3-diselenole was prepared and condensed with dithiolium phoshonium bromides and dithiolium phosphonates in the presence of base to. give dendralene-type vinylogs of TTF bearing a 1,3-diselenole moiety. The electrochemistry of these dendrimers was studied. SEEPR measurements were also carried out. Calculations were carried out on the radical cations and correlated with the EPR values.
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页码:7757 / 7764
页数:8
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