Metallaborane reaction chemistry Part 8.: Phenylacetylene trimerisation by [6,6,6-(PPh3)2H-nido-6-IrB9H13] and the structure of [2-(η6-C6H3Ph3)-closo-2-IrB9H8-10-(PPh3)] by synchrotron X-ray diffraction analysis

被引：11

作者：

Bould, J

Clegg, W

Spalding, TR

Kennedy, JD ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Natl Univ Ireland Univ Coll Cork, Dept Chem, Cork, Ireland

[3] SERC, Daresbury Lab, CLRC, Warrington WA4 4AD, Cheshire, England

[4] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

borane clusters; iridium-borane complexes; crystal structures; synchrotron; metallaborane alkyne oligomerisation;

D O I：

10.1016/S1387-7003(99)00076-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The microwave-heated reaction between PhC drop CH and [6,6,6-(PPh3)(2)H-nido-6-IrB9H13] gives [2-(eta(6)-C6H3Ph3)-closo-2-IrB9H6-10(PPh3)] (29%) and thereby demonstrates acetylene trimerisation on a metallaborane matrix. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：315 / 318

页数：4

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