Sulfonated Polyimides

被引：82

作者：

Marestin, Catherine ^{[2
]}

Gebel, Gerard ^{[1
]}

Diat, Olivier ^{[1
]}

Mercier, Regis ^{[2
]}

机构：

[1] CEA, INAC, Grp Polymeres Conducteurs Ion UMR 5819, CNRS,UJF, F-38054 Grenoble 9, France

[2] Lab Mat Organ Proprietes Specif, UMR 5041, F-69360 Solaize, France

来源：

FUEL CELLS II | 2008年 / 216卷 / 185-258期

基金：

英国工程与自然科学研究理事会;

关键词：

Degradation; Fuel cells; Polymer synthesis; Proton exchange membranes; Structure; Sulfonated polyimides; Transport properties;

D O I：

10.1007/12_2008_155

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Sulfonated polyimides have been designed to be used as proton conducting membranes in fuel cells. These materials present most of the required properties for this application, including a high level of ionic conductivity, a low gas and methanol permeability, and good mechanical properties. However, they exhibit a low stability when immersed in liquid water and in hydrogen peroxide solutions at elevated temperature due to a high sensitivity of the imide functions to hydrolysis. The aim of this article is to review the different routes of synthesis, the membrane-specific properties, the structural and transport property characteristics, and finally their behavior in fuel cells in terms of performance and stability.

引用

页码：185 / 258

页数：74

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