Two distinct solvated structures of p-nitroaniline in acetonitrile

被引：13

作者：

Mohanalingam, K

Hamaguchi, H

机构：

[1] KANAGAWA ACAD SCI & TECHNOL, MOL SPECT LAB, KAWASAKI, KANAGAWA 213, JAPAN

[2] UNIV TOKYO, GRAD SCH ARTS & SCI, DEPT BASIC SCI, MEGURO KU, TOKYO 153, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 02期

关键词：

D O I：

10.1246/cl.1997.157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The presence of two distinct forms of p-nitroaniline (pNA) associated with solvent acetonitrile (AN) molecules is shown by using an SVD (Singular Value Decomposition) analysis of the UV-VIS spectra of pNA in AN/CCl4, mixed solvents. All the three species (including the unassociated form in pure CCl4) observed have varying degrees of intramolecular charge transfer due to the association.

引用

页码：157 / 158

页数：2

共 4 条

[1]

MOHANALINGAM K, 1996, S MOL STRUCT MOL SPE

[2] HYDROGEN-BONDING OF AROMATIC-AMINES IN HYDROXYLIC SOLVENTS .1. ABSORPTION-SPECTROSCOPY OF SUBSTITUTED ANILINES AND HYDROGEN BOND-INDUCED REHYBRIDIZATION OF TRIVALENT NITROGEN-ATOMS [J].