Electrical and electrochemical properties of the 70Li2S•(30-x)P2S5•xP2O5 glass-ceramic electrolytes

被引：45

作者：

Minami, Keiichi ^{[1
]}

Hayashi, Akitoshi ^{[1
]}

Tatsumisago, Masahiro ^{[1
]}

机构：

[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Naka Ku, Osaka 5998531, Japan

来源：

SOLID STATE IONICS | 2008年 / 179卷 / 27-32期

关键词：

solid electrolyte; glass-ceramic; oxysulfide; lithium ion conductivity; all-solid-state lithium secondary battery;

D O I：

10.1016/j.ssi.2008.02.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrical and electrochemical properties of the 70Li(2)S center dot(30-x)P2S5 center dot xP(2)O(5) glass-ceramics were investigated. The glass-ceramics with up to 5 mol% of P2O5 kept high conductivity over 10(-3) S cm(-1). The 70Li(2)S center dot 27P(2)S(5)center dot 3P(2)O(5) glass-ceramic exhibited the highest conductivity of 3.0 x 10(-3) S cm(-1) at room temperature and the lowest activation energy of 16 W mol(-1) for conduction. Electrochemical stability of the glass-ceramic was improved by substituting 3 mol% of P2O5 for P2S5 because the oxygen-incorporated Li7P3S11 crystal would be precipitated in the glass-ceramic. The all-solid-state cell using the 70Li(2)S center dot 27P(2)S(5)center dot 3P(2)O(5) oxysulfide glass-ceramic worked as a lithium secondary battery at room temperature. (C) 2008 Elsevier B.V All rights reserved.

引用

页码：1282 / 1285

页数：4

共 9 条

[1]

Hayashi A, 2001, J AM CERAM SOC, V84, P477, DOI 10.1111/j.1151-2916.2001.tb00685.x

[2] A new amorphous lithium-ion conductor in the system Li2S-P2S3 [J].

Machida, N ;

Yamamoto, H ;

Shigematsu, T .

CHEMISTRY LETTERS, 2004, 33 (01) :30-31

[3] SUPERIONIC CONDUCTION IN LI2S-P2S5-LII-GLASSES [J].

MERCIER, R ;

MALUGANI, JP ;

FAHYS, B ;

ROBERT, G .

SOLID STATE IONICS, 1981, 5 (OCT) :663-666

[4] Structure and properties of the 70Li2S•(30-x)P2S5 • xP2O5 oxysulfide glasses and glass-ceramics [J].

Minami, Keiichi ;

Mizuno, Fuminori ;

Hayashi, Akitoshi ;

Tatsumisago, Masahiro .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2008, 354 (2-9) :370-373

[5] Lithium ion conductivity of the Li2S-P2S5 glass-based electrolytes prepared by the melt quenching method [J].

Minami, Keiichi ;

Mizuno, Fuminori ;

Hayashi, Akitoshi ;

Tatsumisago, Masahiro .

SOLID STATE IONICS, 2007, 178 (11-12) :837-841

[6] Preparation and characterization of lithium ion-conducting oxysulfide glasses [J].

Minami, T ;

Hayashi, A ;

Tatsumisago, M .

SOLID STATE IONICS, 2000, 136 :1015-1023

[7] New, highly ion-conductive crystals precipitated from Li2S-P2S5 glasses [J].

Mizuno, F ;

Hayashi, A ;

Tadanaga, K ;

Tatsumisago, M .

ADVANCED MATERIALS, 2005, 17 (07) :918-+

[8]

TATSUMISAGO M, 1993, NIPPON SERAM KYO GAK, V101, P1315, DOI 10.2109/jcersj.101.1315

[9] Crystal structure of a superionic conductor, Li7P3S11 [J].

Yamane, Hisanori ;

Shibata, Masatoshi ;

Shimane, Yukio ;

Junke, Tadanori ;

Seino, Yoshikatsu ;

Adams, Stefan ;

Minami, Keilchi ;

Hayashi, Akitoshi ;

Tatsumisago, Masahiro .

SOLID STATE IONICS, 2007, 178 (15-18) :1163-1167

← 1 →