Unprecedented Route to Ordered Polyaniline: Direct Synthesis of Highly Crystalline Fibrillar Films with Strong π-π Stacking Alignment

被引：40

作者：

Gospodinova, Natalia ^{[1
,2
]}

Ivanov, Dimitri A. ^{[1
]}

Anokhin, Denis V. ^{[1
]}

Mihai, Iulia ^{[1
]}

Vidal, Loic ^{[1
]}

Brun, Sulyvan ^{[1
]}

Romanova, Julia ^{[1
,3
]}

Tadjer, Alia ^{[3
]}

机构：

[1] Inst Chim Surfaces & Interfaces, F-68057 Mulhouse, France

[2] Ecole Natl Super Chim, F-68093 Mulhouse, France

[3] Univ Sofia, Fac Chem, Sofia 1164, Bulgaria

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2009年 / 30卷 / 01期

关键词：

conducting polymers; highly oriented films; polyaniline; SEM; X-ray; COUNTERION-INDUCED PROCESSIBILITY; CONDUCTING POLYANILINE; ORIENTATION; TRANSPORT; DIFFRACTION; POLYMERS; DOPANTS; SALTS;

D O I：

10.1002/marc.200800434

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Films of polyaniline (PANI) featuring about 80% crystallinity and characterised with strong pi-pi stacking alignment parallel to the film surface have been obtained directly after the original synthesis upon simple drying of the aqueous PANI suspension. A strong anisotropy in the growth of the nano-sized crystals produced during the synthesis results in the formation of micrometer-length fibrils perpendicular to the film surface in the course of water evaporation. The regular intercalation of water molecules between the PANI chains seems to be crucial for their ordering throughout the synthesis and film formation.

引用

页码：29 / 33

页数：5

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