Elaboration of the bis(pyrazolyl)hydroborato ligand [Bp(Bu-t,Pr-i)] into the NNO donor ligand, [(MeO)Bp(Bu-t,Pr-i)]: Structural characterization of a complex in which the [(MeO)Bp(Bu-t,Pr-i)] ligand models the binding of zinc to the peptide backbone in thermolysin

被引：55

作者：

Dowling, C ^{[1
]}

Parkin, G ^{[1
]}

机构：

[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

来源：

POLYHEDRON | 1996年 / 15卷 / 14期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0277-5387(96)00014-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bis(pyrazolyl)hydroborato ligand in (Bp(But,Pri))ZnMe is converted to the NNO donor ligand in [eta(3)-(MeO)Bp(But,Pri)]ZnMe by insertion of [CH2O] into one of the B-H bonds; structural characterization by X-ray diffraction confirms that the ligand binds to the zinc centre in a manner analogous to the binding of zinc to the peptide backbone in thermolysin. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：2463 / 2465

页数：3

共 31 条

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