Synthesis and structural characterization of a tetrahedral sp(3) carbide cluster compound

被引：22

作者：

Takahashi, Y ^{[1
]}

Akita, M ^{[1
]}

Morooka, Y ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 16期

关键词：

D O I：

10.1039/a702806g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of the (mu(3)-halomethylidyne)tricobalt cluster compound (mu(3)-X-C)Co-3(CO)(6)L-3 With Na[Ru(eta-C5H5)(CO)(2)] produces the heptanuclear (mu(5)-C)(eta-C5H5)(2)Ru-2- Co4Hg(CO)(13) 2 [X = Br; L-3 = (CO)(3)] and tetranuclear carbide cluster compound (eta-C5H5)(CO)(2)Ru(mu(4)-C)Co-3-(CO)(6)(tdpm) 4 [X = Cl; L-3 = CH(PPh2)(3) (tdpm)], via substitution of mu(3)-X-C; the latter complex 4 is the first example of a structurally characterized tetrahedral sp(3) carbide cluster compound.

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页码：1557 / 1558

页数：2

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