n-pentane and n-hexane as coguests in structure-H hydrates in mixtures of 2,2-dimethylbutane and methane

被引：20

作者：

Lee, J ^{[1
]}

Lu, HL ^{[1
]}

Moudrakovski, IL ^{[1
]}

Ratcliffe, CI ^{[1
]}

Ripmeester, JA ^{[1
]}

机构：

[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A OR6, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 15期

关键词：

alkanes; clathrates; hydrates; natural gas; NMR spectroscopy;

D O I：

10.1002/anie.200504366

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Room for two little ones? n-Pentane and n-hexane, previously regarded as nonhydrate forming, are found to form structure-H (sH) hydrates in mixtures with 2,2-dimethylbutane. Even though they are thought to be too large to fit into the largest cage of the sH hydrate, powder X-ray diffraction and NMR measurements show that they form gas hydrates in mixtures with other sH-hydrate formers. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2456 / 2459

页数：4

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