Chemical generation and reactivity of C602-.: High-yield and regioselective alkylation of [60, Ih] fullerene

被引：63

作者：

Allard, E ^{[1
]}

Rivière, L ^{[1
]}

Delaunay, J ^{[1
]}

Dubois, D ^{[1
]}

Cousseau, J ^{[1
]}

机构：

[1] Univ Angers, CNRS, UMR 6501, Lab Ingenierie Mol & Mat Organ, F-49045 Angers 01, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(99)01467-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chemical generation of the dianion of C-60 followed by the reaction of monoiodo- or alpha,omega-diiodo-alkanes leads to the high-yield and regioselective formation of 1,2- and 1,4- dialkyl C-60 or 1,2-fused ring C-60 adducts. C-13 NMR studies including proton-carbon correlations were used to ascertain the geometry of the products while the new closed adducts were also characterized by MS, W-vis and voltammetric measurements. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：7223 / 7226

页数：4

共 13 条

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