Correlation between structural and solution calorimetric data for CpRu(PR3)2Cl (Cp = C5Me5) complexes

被引：29

作者：

Smith, DC

Haar, CM

Luo, LB

Li, CB

Cucullu, ME

Mahler, CH

Nolan, SP ^{[1
]}

Marshall, WJ

Jones, NL

Fagan, PJ

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] EI Dupont de Nemours & Co, Expt Stn, Cent Res & Dev Dept, Wilmington, DE 19880 USA

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 12期

关键词：

D O I：

10.1021/om990090k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single-crystal X-ray diffraction studies were conducted bn the following compounds: Cp*Ru(PMe3)(2)Cl (1), Cp*Ru(PPhMe2)(2)Cl (2), Cp*Ru(PMePh2)(2)Cl (3), Cp*Ru(PPh3)(2)Cl (4), Cp*Ru(PEt3)(2)Cl (5), Cp*Ru(AsEt3)(2)Cl (6), Cp*Ru((PBu3)-Bu-n)(2)Cl (7), and Cp*Ru(dmpm)Cl (8). Structural information obtained from these X-ray studies can be correlated with enthalpies of ligand substitution previously determined from solution calorimetry. The cone angle of the phosphine ligand (monodentate) and the Ru-P bond distance were found to be proportional to the enthalpy of reaction.

引用

页码：2357 / 2361

页数：5

共 30 条

[1] Structural studies on substituted pentaruthenium carbido carbonyl clusters
Burrow, RA
Farrar, DH
Hao, JB
Lough, A
Mourad, O
Poe, AJ
Zheng, Y
[J]. POLYHEDRON, 1998, 17 (17) : 2907 - 2919
[2] PENTACOORDINATE FE(CO)3 COMPLEXES OF DIPHOSPHINE LIGANDS WITH BITE ANGLES GREATER THAN 120-DEGREES
CASEY, CP
WHITEKER, GT
CAMPANA, CF
POWELL, DR
[J]. INORGANIC CHEMISTRY, 1990, 29 (18) : 3376 - 3381
[3] ENTHALPIES OF REACTION OF (ETA-5-C5H5)RU(CYCLOOCTADIENE)CL WITH TERTIARY PHOSPHINE-LIGANDS - LIGAND SUBSTITUTION AS A GAUGE FOR METAL BASICITY AND A LINEAR CORRELATION OF BOND-LENGTH AND BOND ENTHALPY
CUCULLU, ME
LUO, LB
NOLAN, SP
FAGAN, PJ
JONES, NL
CALABRESE, JC
[J]. ORGANOMETALLICS, 1995, 14 (01) : 289 - 296
[4] STRUCTURE AND CHEMISTRY OF THE COMPLEX TETRAKIS(ETA-5-PENTAMETHYLCYCLOPENTADIENYL)TETRAKIS(MU-3-CHLORO)-TETRARUTHENIUM(II) - A USEFUL PRECURSOR TO (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(0), (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(II), AND (PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM(IV) COMPLEXES
FAGAN, PJ
MAHONEY, WS
CALABRESE, JC
WILLIAMS, ID
[J]. ORGANOMETALLICS, 1990, 9 (06) : 1843 - 1852
[5] GUZEI IA, UNPUB ACTA CRYSTAL C
[6] Synthetic, thermochemical, and catalytic studies involving novel R2P(ORf) [R = alkyl or aryl; Rf = CH2CH2(CF2)5CF3] ligands
Haar, CM
Huang, J
Nolan, SP
Petersen, JL
[J]. ORGANOMETALLICS, 1998, 17 (23) : 5018 - 5024
[7] HOFF CD, 1992, PROG INORG CHEM, V40, P503
[8] Thermodynamics of phosphine coordination to the [PNP]RhI fragment:: An example of the importance of reorganization energies in the assessment of metal-ligand "Bond Strengths"
Huang, JK
Haar, CM
Nolan, SP
Marshall, WJ
Moloy, KG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (31) : 7806 - 7815
[9] SOLUTION THERMOCHEMICAL STUDY OF LIGAND STERIC INFLUENCES ON SUBSTITUTION ENTHALPIES IN THE L(2)FE(CO)(3) SYSTEM
LI, CB
STEVENS, ED
NOLAN, SP
[J]. ORGANOMETALLICS, 1995, 14 (08) : 3791 - 3797
[10] Solution thermochemical and structural studies of ligand substitution of N-pyrrolyl-substituted phosphine ligands in the Cp'Ru(PR(3))(2)Cl (Cp'=eta(5)-C5H5 and eta(5)-C(5)Me(5)) systems
Li, CB
Serron, S
Nolan, SP
Petersen, JL
[J]. ORGANOMETALLICS, 1996, 15 (19) : 4020 - 4029

← 1 2 3 →

Correlation between structural and solution calorimetric data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) complexes

Correlation between structural and solution calorimetric data for CpRu(PR3)2Cl (Cp = C5Me5) complexes