Synthesis and applications of magnetic nanocomposite catalysts

被引:349
作者
Yi, Dong Kee [1 ]
Lee, Su Seong [1 ]
Ying, Jackie Y. [1 ]
机构
[1] Inst Bioengn & Nanotechnol, Singapore 138669, Singapore
关键词
D O I
10.1021/cm052885p
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis of a nanocomposite of Pd nanoclusters supported on silica-coated Fe2O3 nanocomposite as a magnetic catalyst support due to their superparamagnetic properties and biocompatibility was demonstrated. Self-assembled block copolypeptides on magnetic nanoparticles could be used as a smart drug delivery system controlled by magnetic field. Magnetic nanoparticles can be processed with quantum dots within a silica matrix to yield magnetic and fluorescent nanocomposites. Layer-by-layer synthesis, charged particle interaction, and mercaptosilane functionalization can be employed to derive a novel heterogeneous catalyst system whereby the high surface-to-volume ratio of transmission metal nanoclusters can be used to achieve high reactivity. The transmission electron microscopy results show that Pd nanoclusters were deposited on SiO2/ Fe2O3 nanoparticles with thick SiO2 shell.
引用
收藏
页码:2459 / 2461
页数:3
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