NaBH4/H2O2 fuel cells for air independent power systems

被引:68
作者
Luo, Nie [1 ]
Miley, G. H. [1 ]
Kim, Kyu-Jung [1 ]
Burton, Rodney [2 ]
Huang, Xinyu [3 ]
机构
[1] Univ Illinois, Dept Nucl Engn, Urbana, IL 61801 USA
[2] Univ Illinois, Dept Aerosp Engn, Urbana, IL 61801 USA
[3] Florida Solar Energy Ctr, Cocoa, FL 32922 USA
关键词
Fuel cell; Sodium-borohydride; Peroxide; Ammonia-borane; AIP;
D O I
10.1016/j.jpowsour.2008.08.090
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The performance and characteristics of direct sodium-borohydride/hydrogen-peroxide (NaBH(4)/H(2)O(2)) fuel cells are studied in the context of potential applications for air independent propulsion for outer space and underwater. Due to the existence of ocean (sea) water as a natural heat sink, this new fuel cell technology is best suited for underwater propulsion/power systems for small scale high performance marine vehicles. The characteristics of such a power system are compared to other options, specifically for the underwater scenario. The potential of this fuel cell is demonstrated in laboratory experiments. Power density over 1.5 W cm(-2), at 65 degrees C and ambient pressure. have been achieved with the help of some unique treatments of the fuel cell. One such treatment is an in-situ electroplating technique, which results in electrodes with power density 20-40% higher, than that of the electrodes produced by the ordinary ex-situ electroplating method. This unique process also makes repair or reconditioning of the fuel cell possible and convenient. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:685 / 690
页数:6
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