Comparative sorption kinetic studies of dye and aromatic compounds onto fly ash

被引:338
作者
Ho, YS [1 ]
McKay, G [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Dept Chem Engn, Clear Water Bay, Kowloon, Peoples R China
来源
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING | 1999年 / 34卷 / 05期
关键词
fly ash; kinetics; sorption; dye; o-cresol; p-nitrophenol;
D O I
10.1080/10934529909376889
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A pseudo-second order and a pseudo-first order mechanism for the sorption of Omega Chrome Red ME as well as o-cresol and p-nitrophenol onto fly ash have been compared. Intraparticle diffusion processes and chemical sorption processes for the sorption also have been studied. The batch data for the sorption of Omega Chrome Red ME, o-cresol and p-nitrophenol onto fly ash have been analysed to predict the rate constant of sorption based on the assumption of a pseudo-second order mechanism. The equilibrium capacity and initial sorption rate have also been determined to study the effect of initial solute concentration and temperature on the sorption process. An activation energy of sorption has also been evaluated using the pseudo-second order rate constants.
引用
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页码:1179 / 1204
页数:26
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