Incommensurate antiferromagnetic order in the S=1/2 quantum chain compound LiCuVO4

被引:118
作者
Gibson, B. J. [1 ]
Kremer, R. K. [1 ]
Prokofiev, A. V. [2 ]
Assmus, W. [2 ]
McIntyre, G. J. [3 ]
机构
[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
[2] Goethe Univ Frankfurt, Inst Phys, D-60054 Frankfurt, Germany
[3] Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France
关键词
Incommensurate afm order; Quantum chain compound; Neutron diffraction; Heat capacity;
D O I
10.1016/j.physb.2004.03.064
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The linear spin chain (S = 1/2) compound LiCuVO4 was investigated by elastic neutron diffraction, susceptibility and heat-capacity measurements on single crystals. Long-range incommensurate magnetic ordering with a propagation vector k = (0,0.532,0) is observed below 2.1(1)K by elastic neutron diffraction. The refinement of the magnetic structure indicates that the Cu2+ moments lie within the ab-plane, to enclose an angle of similar to 90 degrees to each other along the chain, and have a magnitude of 0.31(1)mu(B). These findings are attributed to the competition of nearest-and next-nearest-neighbour exchange coupling in the edge-sharing CuO2 chains. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:E253 / E256
页数:4
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