Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d-5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet

被引：80

作者：

Choi, Seok Woo ^{[1
]}

Kwak, Hyun Young ^{[1
]}

Yoon, Jung Hee ^{[1
]}

Kim, Hyoung Chan ^{[2
]}

Koh, Eui Kwan ^{[3
]}

Hong, Chang Seop ^{[1
]}

机构：

[1] Korea Univ, Dept Chem, Seoul 136713, South Korea

[2] Natl Fus Res Inst, Taejon 305333, South Korea

[3] Korea Basic Sci Inst, Nanobio Syst Res Team, Seoul 136713, South Korea

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 22期

关键词：

D O I：

10.1021/ic801699p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Assembling [W(CN)(6)(bpy)](-) and magnetic anisotropic Mn Schiff bases produced two Mn-III(3d)-W-V(5d) bimetallic chains. Modulation of the types and degrees of interchain pi-pi interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property.

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页码：10214 / 10216

页数：3

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