Structure and thermal stability of gold nanoplates - art. no. 071904

被引:37
作者
Kan, CX [1 ]
Wang, GH
Zhu, XG
Li, CC
Cao, BQ
机构
[1] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Dept Phys, Nanjing 210093, Peoples R China
[3] Chinese Acad Sci, Inst Solid State Phys, Hefei 230031, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
D O I
10.1063/1.2175500
中图分类号
O59 [应用物理学];
学科分类号
摘要
Gold (Au) nanoplates with an average thickness of similar to 70 nm and several 10 mu m in edge size have been mass synthesized through a solution-phase method. Structural studies demonstrate that the Au nanoplates are single crystals with (111) planes as two basal surfaces. Fragmentation of Au nanoplates is found when temperature is higher than 450 degrees C. Investigations on the thermal stability of Au nanoplates suggest that the melting and breaking start mainly at the (110) bounded edges, while the (111) surfaces of Au nanoplates show high stability. This work is valuable for Au nanostructures applied at elevated temperatures.
引用
收藏
页数:3
相关论文
共 24 条
  • [1] Biological applications of high aspect ratio nanoparticles
    Bauer, LA
    Birenbaum, NS
    Meyer, GJ
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (04) : 517 - 526
  • [2] INCOMPLETE MELTING OF THE AU(100) SURFACE
    BILALBEGOVIC, G
    TOSATTI, E
    [J]. PHYSICAL REVIEW B, 1993, 48 (15): : 11240 - 11248
  • [3] SIZE EFFECT ON MELTING TEMPERATURE OF GOLD PARTICLES
    BUFFAT, P
    BOREL, JP
    [J]. PHYSICAL REVIEW A, 1976, 13 (06) : 2287 - 2298
  • [4] ANOMALOUS THERMAL-EXPANSION OF NI(001)
    CAO, YJ
    CONRAD, E
    [J]. PHYSICAL REVIEW LETTERS, 1990, 65 (22) : 2808 - 2811
  • [5] MELTING AND NONMELTING BEHAVIOR OF THE AU(111) SURFACE
    CARNEVALI, P
    ERCOLESSI, F
    TOSATTI, E
    [J]. PHYSICAL REVIEW B, 1987, 36 (12): : 6701 - 6704
  • [6] Gold nanocages: Bioconjugation and their potential use as optical imaging contrast agents
    Chen, J
    Saeki, F
    Wiley, BJ
    Cang, H
    Cobb, MJ
    Li, ZY
    Au, L
    Zhang, H
    Kimmey, MB
    Li, XD
    Xia, YN
    [J]. NANO LETTERS, 2005, 5 (03) : 473 - 477
  • [7] Silver nanoplates: Size control in two dimensions and formation mechanisms
    Chen, SH
    Carroll, DL
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (18) : 5500 - 5506
  • [8] Size-dependent melting of silica-encapsulated gold nanoparticles
    Dick, K
    Dhanasekaran, T
    Zhang, ZY
    Meisel, D
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (10) : 2312 - 2317
  • [9] MELTING OF SMALL GOLD PARTICLES - MECHANISM AND SIZE EFFECTS
    ERCOLESSI, F
    ANDREONI, W
    TOSATTI, E
    [J]. PHYSICAL REVIEW LETTERS, 1991, 66 (07) : 911 - 914
  • [10] OBSERVATION OF SURFACE MELTING
    FRENKEN, JWM
    VANDERVEEN, JF
    [J]. PHYSICAL REVIEW LETTERS, 1985, 54 (02) : 134 - 137