Performance of Au/TiO2 catalyst under ambient conditions

被引:136
作者
Daté, M
Ichihashi, Y
Yamashita, T
Chiorino, A
Boccuzzi, F
Haruta, A
机构
[1] Natl Inst Adv Ind Sci & Technol, Ikeda 5638577, Japan
[2] Univ Turin, Dipartimento Chim IFM, I-10125 Turin, Italy
关键词
gold catalysts; carbon monoxide oxidation; moisture; calcination temperature; regeneration;
D O I
10.1016/S0920-5861(01)00481-3
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The catalytic activity and stability of Au/TiO2 have been examined under ambient conditions. The best performance was obtained for a catalyst calcined at 473 K and left at room temperature for a few days. The activity for CO oxidation was greatly influenced by moisture in the reactant gas and a maximum was observed at around 200 ppm. We have also succeeded in regenerating the catalysts exposed to various environments, such as rest room, using irradiation with light. The above results show that the Au/TiO2 catalysts are very useful for indoor air quality control at room temperature without using thermal energy for regeneration. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:89 / 94
页数:6
相关论文
共 17 条
  • [1] Au/TiO2 nanosized samples:: A catalytic, TEM, and FTIR study of the effect of calcination temperature on the CO oxidation
    Boccuzzi, F
    Chiorino, A
    Manzoli, M
    Lu, P
    Akita, T
    Ichikawa, S
    Haruta, M
    [J]. JOURNAL OF CATALYSIS, 2001, 202 (02) : 256 - 267
  • [2] A kinetic and DRIFTS study of low-temperature carbon monoxide oxidation over Au-TiO2 catalysts
    Bollinger, MA
    Vannice, MA
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1996, 8 (04) : 417 - 443
  • [3] Gold-catalysed oxidation of carbon monoxide
    Bond, GC
    Thompson, DT
    [J]. GOLD BULLETIN, 2000, 33 (02) : 41 - 51
  • [4] INFLUENCE OF DRY OPERATING-CONDITIONS - OBSERVATION OF OSCILLATIONS AND LOW-TEMPERATURE CO OXIDATION OVER CO3O4 AND AU/CO3O4 CATALYSTS
    CUNNINGHAM, DAH
    KOBAYASHI, T
    KAMIJO, N
    HARUTA, M
    [J]. CATALYSIS LETTERS, 1994, 25 (3-4) : 257 - 264
  • [5] Negative activation energies in CO oxidation over an icosahedral Au/Mg(OH)2 catalyst
    Cunningham, DAH
    Vogel, W
    Haruta, M
    [J]. CATALYSIS LETTERS, 1999, 63 (1-2) : 43 - 47
  • [6] Moisture effect on CO oxidation over Au/TiO2 catalyst
    Daté, M
    Haruta, M
    [J]. JOURNAL OF CATALYSIS, 2001, 201 (02) : 221 - 224
  • [7] LOW-TEMPERATURE OXIDATION OF CO OVER GOLD SUPPORTED ON TIO2, ALPHA-FE2O3, AND CO3O4
    HARUTA, M
    TSUBOTA, S
    KOBAYASHI, T
    KAGEYAMA, H
    GENET, MJ
    DELMON, B
    [J]. JOURNAL OF CATALYSIS, 1993, 144 (01) : 175 - 192
  • [8] Size- and support-dependency in the catalysis of gold
    Haruta, M
    [J]. CATALYSIS TODAY, 1997, 36 (01) : 153 - 166
  • [9] HARUTA M, 1991, CAT SCI TEC, V1, P331
  • [10] Selective vapor-phase epoxidation of propylene over Au/TiO2 catalysts in the presence of oxygen and hydrogen
    Hayashi, T
    Tanaka, K
    Haruta, M
    [J]. JOURNAL OF CATALYSIS, 1998, 178 (02) : 566 - 575