Magnetic resonance experiments on the green emission in undoped ZnO crystals

被引:65
作者
Leiter, F [1 ]
Zhou, H [1 ]
Henecker, F [1 ]
Hofstaetter, A [1 ]
Hofmann, DM [1 ]
Meyer, BK [1 ]
机构
[1] Univ Giessen, Phys Inst 1, D-35625 Giessen, Germany
关键词
ZnO; optically detected magnetic resonance; anion vacancies;
D O I
10.1016/S0921-4526(01)00837-7
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Optically detected magnetic resonance shows that a broad, green emission band in ZnO at 2.45 eV originates from a spintriplet-recombination characterised by g(parallel toc) = 1.984 and g(perpendicular toc) = 2.025 (parallel and perpendicular to the crystallographic c-axis, respectively) and a zero-field splitting of D = 260 x 10(-4)cm(-1). These parameters and the polarisation properties of the emission are very similar to the anion vacancies in CaO but not compatible with the Zeeman results on ZnO:Cu. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:908 / 911
页数:4
相关论文
共 7 条
[1]   FINE-STRUCTURE AND ZEEMAN EFFECT OF THE EXCITED-STATE OF THE GREEN EMITTING COPPER CENTER IN ZINC-OXIDE [J].
BROSER, IJ ;
GERMER, RKF ;
SCHULZ, HJE ;
WISZNEWSKI, KP .
SOLID-STATE ELECTRONICS, 1978, 21 (11-1) :1597-1602
[2]   OPTICAL DETECTION OF PARAMAGNETIC-RESONANCE IN EXCITED-STATE OF F CENTERS IN CAO [J].
EDEL, P ;
HENNIES, C ;
DAUBIGNE, YM ;
ROMESTAI.R ;
TWAROWSK.Y .
PHYSICAL REVIEW LETTERS, 1972, 28 (19) :1268-+
[3]   First-principles study of native point defects in ZnO [J].
Kohan, AF ;
Ceder, G ;
Morgan, D ;
Van de Walle, CG .
PHYSICAL REVIEW B, 2000, 61 (22) :15019-15027
[4]   VIBRONIC STRUCTURE OF THE GREEN PHOTO-LUMINESCENCE DUE TO COPPER IMPURITIES IN ZNO [J].
KUHNERT, R ;
HELBIG, R .
JOURNAL OF LUMINESCENCE, 1981, 26 (1-2) :203-206
[5]   Electrical properties of bulk ZnO [J].
Look, DC ;
Reynolds, DC ;
Sizelove, JR ;
Jones, RL ;
Litton, CW ;
Cantwell, G ;
Harsch, WC .
SOLID STATE COMMUNICATIONS, 1998, 105 (06) :399-401
[6]  
MINEGISHI K, 1997, JPN J APPL PHYS, V36, pL1452
[7]   PARAMAGNETISCHE RESONANZ VON DONATOREN IN ZINKOXYD [J].
SCHNEIDER, J ;
RAUBER, A .
ZEITSCHRIFT FUR NATURFORSCHUNG PART A-ASTROPHYSIK PHYSIK UND PHYSIKALISCHE CHEMIE, 1961, 16 (07) :712-714