Multifunctional chemical vapor sensors of aligned carbon nanotube and polymer composites

Partially coating perpendicularly aligned carbon nanotube arrays with an appropriate polymer thin film along their tube length provides a novel concept for developing new sensors of high sensitivity, good selectivity, and excellent environmental stability for the detection of a broad class of chemical vapors with low power consumption. The absorption and desorption of chemical vapors by the polymer matrix cause changes in the inter-tube distance and, hence, the surface resistance across the nanotube film. Simple measurements of the resistance change, therefore, constitute the nanotube-polymer chemical vapor sensors. These rationally designed, aligned carbon nanotube-polymer composite films are flexible and can be effectively integrated into many systems for a wide range of potential applications, including their use as multifunctional sensors for sensing chemical vapors, mechanical deformations, thermal and optical exposures. Copyright © 2006 American Chemical Society.