Instrumental developments in capillary electrochromatography

被引：84

作者：

Rebscher, H ^{[1
]}

Pyell, U ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY

来源：

CHROMATOGRAPHIA | 1996年 / 42卷 / 3-4期

关键词：

liquid chromatography; electrochromatography; slurry packed capillaries; polycyclic aromatic hydrocarbons;

D O I：

10.1007/BF02269648

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

An instrumental device for capillary electrochromatography (CEC) is described that permits conditioning of packed columns at pressures up to 100 bar, in or on-column fluorescence detection and electrokinetic sample injection. Capillaries with varying inner diameters (75, 100, 150 mu m) packed with octadecyl silica gel (3 mu m) are compared for efficiency and detection sensitivity. The influence of counter pressure on electroosmotic velocity and plate number is discussed.

引用

页码：171 / 176

页数：6

共 16 条

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