Determination of some metal ions in aquatic environs by atomic absorption spectrometry after concentration with modified silica

被引:2
作者
Hamed, Mohamed A.
Abou-El-Sherbini, Khaled S.
Lotfy, Hesham R. [1 ]
机构
[1] Univ Namibia, Dept Chem, Windhoek, Namibia
[2] Natl Inst Oceanog & Fisheries, Suez, Egypt
[3] Natl Res Ctr Dokki, Cairo, Egypt
关键词
determination; trace heavy metal ions; modified silica; natural waters;
D O I
10.1002/jccs.200600079
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The uptake behavior of porous silica modified with N-propylsalicylaldimine (IE11) for Cd(II), Cr(III), Cu(II), Mn(II) and Pb(II) metal ions were studied. The Log k(d) values were found to be within the range 2.19-5.16 depending on pH and time of stirring. IE11 was used in the separation and preconcentration of Cd(II), Cr(III), Cu(II), Mn(II) and Pb(II) from some natural water samples. The data were compared with those obtained by the solvent extraction method (APDC/MIBK). The method was found to be accurate and precise and not subject to random error.
引用
收藏
页码:605 / 612
页数:8
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