Transition metal-catalyzed dehydrogenative germylation of olefins with tri-n-butylgermane

被引：27

作者：

Furukawa, N

Kourogi, N

Seki, Y ^{[1
]}

Kakiuchi, F

Murai, S

机构：

[1] Kagawa Univ, Fac Econ, Lab Commod Sci, Kagawa 7608523, Japan

[2] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 5650871, Japan

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 18期

关键词：

D O I：

10.1021/om990336l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The catalyzed reaction of an excess of styrene with n-Bu3GeH using several ruthenium and rhodium complexes gave the corresponding vinylgermanes (alpha-tri-n-butylgermylstyrene, (Z)-beta-tri-12-butylgermylstyrene, and (E)-beta-tri-n-butylgermylstyrene), which are dehydrogenative germylation products. The most effective catalyst was Ru-3(CO)(12) whose use resulted in selective formation of the vinylgermanes in high yields.

引用

页码：3764 / 3767

页数：4

共 37 条

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[2]

CHAN TH, 1979, SYNTHESIS-STUTTGART, P761

[3]

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